Insights into the general circulation of the lower stratosphere from TOMS

Total ozone is controlled by dynamical advection as well as chemistry. At least for day-to-day variations, dynamical processes appear to be in control of total ozone. There also appears to be good evidence that seasonal and secular changes in total ozone are also dynamically controlled. For example, the zonal mean changes in total ozone in the two hemispheres in spring appear to be quite different. The TOMS total ozone data suggest a south polar spring upwelling while the Northern Hemisphere shows a clear downwelling in the same period. Radiative transfer computations support this conclusion. The secular changes in total ozone over the South Pole in spring indicate a change in dynamics rather than chemistry

Water Vapor and Cloud Formation in the TTL: Simulation Results vs. Satellite Observations

Driven by analyzed winds and temperature, domain-filling forward trajectory calculations are used to reproduce water vapor and cloud formations in the tropical tropopause layer (TTL). As with most Lagrangian models of this type, excess water vapor is instantaneously removed from the parcel to keep the relative humidity with respect to ice from exceeding a specified (super) saturation level. The dehydration occurrences serve as an indication of where and when cloud forms. Convective moistening through ice lofting and gravity waves are also included in our simulations as mechanisms that could affect water vapor abundances and cloud formations in the TTL. Our simulations produce water vapor mixing ratios close to that observed by the Aura Microwave Limb Sounder (MLS) and are consistent with the reanalysis tropical tropopause temperature biases, which proves the importance of the cold-point temperature to the water vapor abundances in the stratosphere. The simulation of cloud formation agrees with the patterns of cirrus distribution from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO). It proves that the trajectory calculations fed by the analyzed wind and temperature could produce reasonable simulations of water vapor and cloud formation in the TTL

The breakup of the Southern Hemisphere spring polar ozone and temperature minimums from 1979 to 1987

The purpose of this study is to quantify the observations of the polar vortex breakup. The data used in this study consist of Total Ozone Mapping Spectrometer (TOMS) data, and National Meteorological Center (NMC) analyses. The final warming is diagnosed using the difference between zonal means at 80 degrees and 50 degrees S for temperature, ozone, and layer mean temperature. The polar vortex breakup can also be diagnosed by the onset of weak zonal mean zonal winds (i.e., u, overbar denotes a zonal average) at 60 degrees S. Computations of the polar vortex breakdown date using NMC meteorological data and TOMS total ozone data indicate that the breakdown is occurring later in the spring in the lowest portion of the stratosphere. At altitudes above 100 mb, the large interannual variance of the breakdown date renders any trend determination of the breakdown date difficult. Individual plots of TOMS total ozone indicate that the total ozone minimum remains intact for a longer period of time than is observed in earlier years

Atmospheric Chemistry and Transport from Space Observations

This lecture will cover the basic ideas of space observations of chemical constituents, modern analysis techniques and results. I will show analysis using TOMS, UARS, SAGE, Terra. I will show some of the planned missions for the US that will launch in the next few years

Estimating stratospheric temperature trends using satellite microwave radiances

The objective was to evaluate and intercompare stratospheric temperatures using Microwave Sounding Unit (MSU) data as a basis data set. The MSU, aboard the NOAA polar orbiter satellite series, provides twice daily global coverage over a layer (50-150 mb) at approximately a (170km)(exp 2) resolution. Conventional data sets will be compared to the satellite data in the lower stratosphere in order to assess their quality for trend computations

Potential impact of subsonic and supersonic aircraft exhaust on water vapor in the lower stratosphere assessed via a trajectory model

We employ a trajectory model to assess the impact on the stratosphere of water vapor present in the exhaust of subsonic and a proposed fleet of supersonic aircraft. Air parcels into which water vapor from aircraft exhaust has been injected are run through a 6-year simulation in the trajectory model using meteorological data from the UKMO analyses with emissions dictated by the standard 2015 emissions scenario. For the subsonic aircraft, our results suggest maximum enhancements of ~150 ppbv just above the Northern Hemisphere tropopause and of much less than 50 ppbv in most other regions. Inserting the perturbed water vapor profiles into a radiative transfer model, but not considering the impact of additional cirrus formation resulting from emissions by subsonic aircraft, we find that the impact of subsonic water vapor emissions on the radiative balance is negligible. For the supersonic case, our results show maximum enhancements of ~1.5 ppmv in the tropical stratosphere near 20 km. Much of the remaining stratosphere between 12 and 25 km sees enhancements of greater than 0.1 ppmv, although enhancements above 35 km are generally less than 50 ppbv, in contrast to previous 2-D and 3-D model studies. Radiative calculations based upon these projected water vapor perturbations indicate they may cause a nonnegligible impact on tropical temperature profiles. Since our trajectory model includes no chemistry and our radiative calculations use the most extreme water vapor perturbations, our results should be viewed as upper limits on the potential impacts

Near-Saturation Conditions at the Tropical Tropopause: Results from Ticosonde

The TTL lies between the neutral buoyancy level (NBL) at ~350 K and the tropopause. Within the the TTL radiative heating drives ascent and air parcel supersaturation. Ticosonde measurements since 2005 show that the incidence ofsupersaturation in the TTL over Costa Rica is ~60%. This is due to diabatic ascent. The frequency is highest (68%) in summer, when convection is frequent. The TSL was defined by Selkirk et al. (2010) as the upper edge of the TTL. It isIn this layer that the final saturation of air parcels rising into the stratosphere occurs and thus the water vapor minima which define the so-called "writehead" of the Atmospheric Tape Recorder

Impact of Convectively Detrained Ice Crystals on the Tropical Upper Troposphere and Lower Stratosphere

The role of convectively detrained ice crystals on the humidity of the tropical upper troposphere and lower stratosphere (UTLS) is investigated in simulations of cirrus clouds along trajectories launched from the 378K potential temperature level in the tropics. The one-dimensional (vertical) cloud model tracks individual ice crystals through their lifecycle beginning with detrainment from convection, followed by deposition growth, sedimentation and sublimation. Convective influence of the parcels is diagnosed by tracing the trajectories through time-dependent fields of convective cloud-top height adjusted to match the CloudSAT and CALIPSO statistics. Model simulations of UTLS water vapor and cloud fields are evaluated and constrained by comparison with Aura MLS and CALIPSO measurements. Preliminary results indicate sensitivity of the detrained ice crystal lifecycle to atmospheric conditions downstream of convection. Specifically, cooling (high relative humidity and supersaturation) downstream of convection leads to deposition growth and sedimentation of detrained ice crystals, resulting in net dehydration of the UTLS. In contrast, warming (low relative humidity and subsaturation) downstream of convection leads to sublimation of detrained ice crystals and subsequent hydration. As such, the impact of detrained ice crystals on the humidity of the UTLS exhibits distinct spatial variability. Detrained ice crystals predominantly dehydrate the UTLS in the tropical mean. Sensitivities to the convectively detrained ice crystal size and concentration are also examined using measurements from the StatoClim aircraft campaign. The importance of convectively detrained ice crystals will be discussed within the context of the overall contribution of convection to the lower stratospheric humidity

Evidence of Convective Redistribution of Carbon Monoxide in Aura Tropospheric Emission Sounder (TES) and Microwave Limb Sounder (MLS) Observations

Vertical convective transport is a key element of the tropospheric circulation. Convection lofts air from the boundary layer into the free troposphere, allowing surface emissions to travel much further, and altering the rate of chemical processes such as ozone production. This study uses satellite observations to focus on the convective transport of CO from the boundary layer to the mid and upper troposphere. Our hypothesis is that strong convection associated with high rain rate regions leads to a correlation between mid level and upper level CO amounts. We first test this hypothesis using the Global Modeling Initiative (GMI) chemistry and transport model. We find the correlation is robust and increases as the precipitation rate (the strength of convection) increases. We next examine three years of CO profiles from the Tropospheric Emission Sounder (TES) and Microwave Limb Sounder (MLS) instruments aboard EOS Aura. Rain rates are taken from the Tropical Rainfall Measuring Mission (TRMM) 3B-42 multi-satellite product. Again we find a correlation between mid-level and upper tropospheric CO, which increases with rain rate. Our result shows the critical importance of tropical convection in coupling vertical levels of the troposphere in the transport of trace gases. The effect is seen most clearly in strong convective regions such as the Inter-tropical Convergence Zone

The Aerosol/Cloud/Ecosystems Mission (ACE)

The goals and measurement strategy of the Aerosol/Cloud/Ecosystems Mission (ACE) are described. ACE will help to answer fundamental science questions associated with aerosols, clouds, air quality and global ocean ecosystems. Specifically, the goals of ACE are: 1) to quantify aerosol-cloud interactions and to assess the impact of aerosols on the hydrological cycle and 2) determine Ocean Carbon Cycling and other ocean biological processes. It is expected that ACE will: narrow the uncertainty in aerosol-cloud-precipitation interaction and quantify the role of aerosols in climate change; measure the ocean ecosystem changes and precisely quantify ocean carbon uptake; and, improve air quality forecasting by determining the height and type of aerosols being transported long distances. Overviews are provided of the aerosol-cloud community measurement strategy, aerosol and cloud observations over South Asia, and ocean biology research goals. Instruments used in the measurement strategy of the ACE mission are also highlighted, including: multi-beam lidar, multiwavelength high spectra resolution lidar, the ocean color instrument (ORCA)--a spectroradiometer for ocean remote sensing, dual frequency cloud radar and high- and low-frequency micron-wave radiometer. Future steps for the ACE mission include refining measurement requirements and carrying out additional instrument and payload studies